51 research outputs found
Structure of liquid and glassy methanol confined in cylindrical pores
We present a neutron scattering analysis of the density and the static
structure factor of confined methanol at various temperatures. Confinement is
performed in the cylindrical pores of MCM-41 silicates with pore diameters D=24
angstrom and D=35 angstrom. A change of the thermal expansivity of confined
methanol at low temperature is the signature of a glass transition, which
occurs at higher temperature for the smallest pore. This is an evidence of a
surface induced slowing down of the dynamics of the fluid. The structure factor
presents a systematic evolution with the pore diameter, which has been analyzed
in terms of excluded volume effects and fluid-matrix cross-correlation.
Conversely to the case of Van der Waals fluids, it shows that stronger
fluid-matrix correlations must be invoked most probably in relation with the
H-bonding character of both methanol and silicate surface.Comment: version March 12 200
Découverte de brachiopodes du Sinémurien dans la Sierra Harana (Subbétique Interne, Cordilleres Bétiques, prov. de Grenade, Espagne). Implications stratigraphiques
Two Lower Sinemurian brachiopod species from the NW european province [Calcirhynchia calcaria Buckman and Calcirhynchia calcicosta (Quenstedt)] have been found for the first time in the lower dolomitic beds of the Lower lurassic carbonate ensemble of the Sierra Harana unit (Internal Subbetic). Their presence allow to detail the evolution of the installation of the carbonate platform in the southern iberian domains during the Lower Lias transgression.Dos especies de braquiópodos del Sinemuriense inferior de la provincia NW europea [Calcirhynchia calcaria Buckman y Calcirhynchia calcicosta (Quenstedt)] han sido encontradas por primera vez en los materiales dolomíticos inferiores del conjunto carbonatado infrajurásico de la Unidad de Sierra Harana (Subbético Interno). Su presencia permite precisar los momentos sucesivos de la implantación de la plataforma carbonatada en el dominio del paleomargen sudibérico durante la transgresión del Lías inferior
Diffusion in pores and its dependence on boundary conditions
We study the influence of the boundary conditions at the solid liquid
interface on diffusion in a confined fluid. Using an hydrodynamic approach, we
compute numerical estimates for the diffusion of a particle confined between
two planes. Partial slip is shown to significantly influence the diffusion
coefficient near a wall. Analytical expressions are derived in the low and high
confinement limits, and are in good agreement with numerical results. These
calculations indicate that diffusion of tagged particles could be used as a
sensitive probe of the solid-liquid boundary conditions.Comment: soumis \`a J.Phys. Cond. Matt. special issue on "Diffusion in
Liquids, Polymers, Biophysics and Chemical Dynamics
and Oxygen Stoichiometry: Structure, Resistivity, Fermi Surface Topology and Normal State Properties
(2212) single crystal samples
were studied using transmission electron microscopy (TEM), plane
() and axis () resistivity, and high resolution
angle-resolved ultraviolet photoemission spectroscopy (ARUPS). TEM reveals that
the modulation in the axis for doped 2212 is dominantly
of type that is not sensitive to the oxygen content of the system, and the
system clearly shows a structure of orthorhombic symmetry. Oxygen annealed
samples exhibit a much lower axis resistivity and a resistivity minimum at
K. He-annealed samples exhibit a much higher axis resistivity and
behavior below 300K. The Fermi surface (FS) of oxygen annealed
2212 mapped out by ARUPS has a pocket in the FS around the
point and exhibits orthorhombic symmetry. There are flat, parallel sections of
the FS, about 60\% of the maximum possible along , and about 30\%
along . The wavevectors connecting the flat sections are about
along , and about along , rather than . The symmetry of the near-Fermi-energy dispersing
states in the normal state changes between oxygen-annealed and He-annealed
samples.Comment: APS_REVTEX 3.0, 49 pages, including 11 figures, available upon
request. Submitted to Phys. Rev. B
Hypersensitive Response-Like Reaction Is Associated with Hybrid Necrosis in Interspecific Crosses between Tetraploid Wheat and Aegilops tauschii Coss
BACKGROUND: Hybrid speciation is classified into homoploid and polyploid based on ploidy level. Common wheat is an allohexaploid species that originated from a naturally occurring interploidy cross between tetraploid wheat and diploid wild wheat Aegilops tauschii Coss. Aegilops tauschii provides wide naturally occurring genetic variation. Sometimes its triploid hybrids with tetraploid wheat show the following four types of hybrid growth abnormalities: types II and III hybrid necrosis, hybrid chlorosis, and severe growth abortion. The growth abnormalities in the triploid hybrids could act as postzygotic hybridization barriers to prevent formation of hexaploid wheat. METHODOLOGY/PRINCIPAL FINDINGS: Here, we report on the geographical and phylogenetic distribution of Ae. tauschii accessions inducing the hybrid growth abnormalities and showed that they are widely distributed across growth habitats in Ae. tauschii. Molecular and cytological characterization of the type III necrosis phenotype was performed. The hybrid abnormality causing accessions were widely distributed across growth habitats in Ae. tauschii. Transcriptome analysis showed that a number of defense-related genes such as pathogenesis-related genes were highly up-regulated in the type III necrosis lines. Transmission electron microscope observation revealed that cell death occurred accompanied by generation of reactive oxygen species in leaves undergoing type III necrosis. The reduction of photosynthetic activity occurred prior to the appearance of necrotic symptoms on the leaves exhibiting hybrid necrosis. CONCLUSIONS/SIGNIFICANCE: Taking these results together strongly suggests that an autoimmune response might be triggered by intergenomic incompatibility between the tetraploid wheat and Ae. tauschii genomes in type III necrosis, and that genetically programmed cell death could be regarded as a hypersensitive response-like cell death similar to that observed in Arabidopsis intraspecific and Nicotiana interspecific hybrids. Only Ae. tauschii accessions without such inhibiting factors could be candidates for the D-genome donor for the present hexaploid wheat
Differential Metabolisms of Green Leaf Volatiles in Injured and Intact Parts of a Wounded Leaf Meet Distinct Ecophysiological Requirements
Almost all terrestrial plants produce green leaf volatiles (GLVs), consisting of six-carbon (C6) aldehydes, alcohols and their esters, after mechanical wounding. C6 aldehydes deter enemies, but C6 alcohols and esters are rather inert. In this study, we address why the ability to produce various GLVs in wounded plant tissues has been conserved in the plant kingdom. The major product in completely disrupted Arabidopsis leaf tissues was (Z)-3-hexenal, while (Z)-3-hexenol and (Z)-3-hexenyl acetate were the main products formed in the intact parts of partially wounded leaves. 13C-labeled C6 aldehydes placed on the disrupted part of a wounded leaf diffused into neighboring intact tissues and were reduced to C6 alcohols. The reduction of the aldehydes to alcohols was catalyzed by an NADPH-dependent reductase. When NADPH was supplemented to disrupted tissues, C6 aldehydes were reduced to C6 alcohols, indicating that C6 aldehydes accumulated because of insufficient NADPH. When the leaves were exposed to higher doses of C6 aldehydes, however, a substantial fraction of C6 aldehydes persisted in the leaves and damaged them, indicating potential toxicity of C6 aldehydes to the leaf cells. Thus, the production of C6 aldehydes and their differential metabolisms in wounded leaves has dual benefits. In disrupted tissues, C6 aldehydes and their α,β-unsaturated aldehyde derivatives accumulate to deter invaders. In intact cells, the aldehydes are reduced to minimize self-toxicity and allow healthy cells to survive. The metabolism of GLVs is thus efficiently designed to meet ecophysiological requirements of the microenvironments within a wounded leaf
Influence of wetting properties on diffusion in a confined fluid
We briefly discuss how the wetting properties of a fluid/solid interface can indirectly influence the diffusion properties of fluid confined between two solid walls. This influence is related to the variability of the hydrodynamic boundary conditions at the interface, which correlates to the wetting properties
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